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Open Access Article
1 - Polymer Networks as Hierarchical Porous Carbon Materials: Synthesize, Properties and Applications
ziba shirini kordabadi Fatemeh RafiemanzelatPorous materials have different types of pores in the micro, meso or nano range, each of which plays a special role in porous materials application. Among these materials, porous carbon materials have a special share due to their unique properties such as: mechanical, c MorePorous materials have different types of pores in the micro, meso or nano range, each of which plays a special role in porous materials application. Among these materials, porous carbon materials have a special share due to their unique properties such as: mechanical, chemical and thermal stability and their reasonable price. There are two main methods for synthesizing porous carbon materials: 1) template method and 2) pyrolysis/activation method. The template method is basically time consuming and tedious due to the use of the template and removal of template. Thus the method of pyrolysis/activation is widely used to prepare porous carbon materials from porous polymer precursers or waste and biomass materials in the presence of the physical and chemical active agents. Replacement of heteroatoms including: N, O, B, S and P in carbon materials leads to increased efficiency and development of their new applications; For example, the use of porous N-doped carbon materials as electrodes in superconducting cells increases the efficiency of energy storage and in the field of adsorbents materials increases the efficiency of CO2 uptake. Due to their unique properties, especially high surface area, low weight and high adsorption capacity, porous carbon materials are used in hydrogen storage, contaminants removal fron air air water, electrodes and as catalyst support. Manuscript profile -
Open Access Article
2 - A review of the sorbents based on covalent organic frameworks containing hybrids for extraction methods
Mohammad Javad Aghajani Milad Ghani Jahan Bakhsh RaoofCovalent organic frameworks have been used as a group of porous organic frameworks due to their remarkable intrinsic properties, such as high specific surface area and variable pore size as well as high stability. Also, they are flexible that by producing functional cov MoreCovalent organic frameworks have been used as a group of porous organic frameworks due to their remarkable intrinsic properties, such as high specific surface area and variable pore size as well as high stability. Also, they are flexible that by producing functional covalent organic frameworks or polystructures based on them, major changes in their physical and chemical properties can be made. In this article, several important groups of covalent organic frameworks are examined in terms of their design and manufacturing methods. Also, synergism of covalent organic frameworks with other materials, such as different types of magnetic nanoparticles, metal/metal oxide, silica, carbon nanomaterials, polymers, polyoxometalates and metal-organic frameworks are studied. Finally, recent applications of covalent organic frameworks as efficient adsorbents in sample preparation methods such as solid phase extraction, diffusion solid phase extraction, magnetic solid phase extraction and fibrous solid phase microextraction with emphasis on important factors that lead to increased efficiency It will be extracted and will be checked. Investigations have shown that hybrid formation of organic-covalent frameworks and other compounds, including polymers, can be effective in improving the performance of these compounds. It is important to note that an essential step during the synthesis of covalent organic frameworks is their design concept. The purpose of design is the specific orientation of covalent bonds between the functional groups of constituents (node and linker), types of bonds and types of topologies with pore sizes that require engineering. In addition, the challenges in these approaches will also be discussed. Manuscript profile
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